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Volume 2, issue 2
Solid Earth, 2, 245-257, 2011
https://doi.org/10.5194/se-2-245-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.

Special issue: Phanerozoic black shales and oceanic anoxic events: geochemistry,...

Solid Earth, 2, 245-257, 2011
https://doi.org/10.5194/se-2-245-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 11 Nov 2011

Research article | 11 Nov 2011

An open ocean record of the Toarcian oceanic anoxic event

D. R. Gröcke1, R. S. Hori2, J. Trabucho-Alexandre1, D. B. Kemp3, and L. Schwark4 D. R. Gröcke et al.
  • 1Department of Earth Sciences, Durham University, Science Laboratories, South Road, Durham, DH1 3LE, UK
  • 2Department of Earth Sciences, Faculty of Science, Ehime University, Matsuyama 790-8577, Japan
  • 3Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge, CB2 3EQ, UK
  • 4Christian-Albrechts-University–Kiel, Institute for Geosciences, Ludewig-Meyn-Str. 10, 24118 Kiel, Germany

Abstract. Oceanic anoxic events were time intervals in the Mesozoic characterized by widespread distribution of marine organic matter-rich sediments (black shales) and significant perturbations in the global carbon cycle. These perturbations are globally recorded in sediments as carbon isotope excursions irrespective of lithology and depositional environment. During the early Toarcian, black shales were deposited on the epi- and pericontinental shelves of Pangaea, and these sedimentary rocks are associated with a pronounced (ca. 7 ‰) negative (organic) carbon isotope excursion (CIE) which is thought to be the result of a major perturbation in the global carbon cycle. For this reason, the lower Toarcian is thought to represent an oceanic anoxic event (the T-OAE). If the T-OAE was indeed a global event, an isotopic expression of this event should be found beyond the epi- and pericontinental Pangaean localities. To address this issue, the carbon isotope composition of organic matter (δ13Corg of lower Toarcian organic matter-rich cherts from Japan, deposited in the open Panthalassa Ocean, was analysed. The results show the presence of a major (>6 ‰) negative excursion in δ13Corg that, based on radiolarian biostratigraphy, is a correlative of the lower Toarcian negative CIE known from Pangaean epi- and pericontinental strata. A smaller negative excursion in δ13Corg (ca. 2 ‰) is recognized lower in the studied succession. This excursion may, within the current biostratigraphic resolution, represent the excursion recorded in European epicontinental successions close to the Pliensbachian/Toarcian boundary. These results from the open ocean realm suggest, in conjunction with other previously published datasets, that these Early Jurassic carbon cycle perturbations affected the active global reservoirs of the exchangeable carbon cycle (deep marine, shallow marine, atmospheric).

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