Articles | Volume 7, issue 2
https://doi.org/10.5194/se-7-441-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/se-7-441-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
24 Mar 2016
Research article |
| 24 Mar 2016
Calculating structural and geometrical parameters by laboratory measurements and X-ray microtomography: a comparative study applied to a limestone sample before and after a dissolution experiment
Institute of Environmental Assessment and Water Research (IDAEA),
Hydrogeology Group (UPC-CSIC), c/ Jordi Girona 18, 08034 Barcelona, Spain
Vanessa Hebert
Voxaya SAS, Cap Omega, Rond-Point Benjamin Franklin, CS 39521,
34960 Montpellier, France
Olivier Rodriguez
Voxaya SAS, Cap Omega, Rond-Point Benjamin Franklin, CS 39521,
34960 Montpellier, France
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Paula Ogilvie and Roger L. Gibson
Solid Earth, 8, 93–135, https://doi.org/10.5194/se-8-93-2017, https://doi.org/10.5194/se-8-93-2017, 2017
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Faisal Khan, Frieder Enzmann, and Michael Kersten
Solid Earth, 7, 481–492, https://doi.org/10.5194/se-7-481-2016, https://doi.org/10.5194/se-7-481-2016, 2016
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X-ray microtomography image processing involves artefact reduction and image segmentation. The beam-hardening artefact is removed, applying a new algorithm, which minimizes the offsets of the attenuation data points. For the segmentation, we propose using a non-linear classifier algorithm. Statistical analysis was performed to quantify the improvement in multi-phase classification of rock cores using and without using our advanced beam-hardening correction algorithm.
E. Berrezueta, B. Ordóñez-Casado, and L. Quintana
Solid Earth, 7, 37–53, https://doi.org/10.5194/se-7-37-2016, https://doi.org/10.5194/se-7-37-2016, 2016
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The aim of this article is to describe and interpret qualitative and quantitative changes at the rock matrix scale of Cretaceous sandstones (northern Spain) exposed to supercritical CO2 and brine. Experimental CO2-rich brine injection was performed in a reactor chamber under realistic conditions of deep saline formations (P ≈ 7.8 MPa, T ≈ 38 °C and 24 h exposure time). SEM and optical microscopy, aided by optical image processing and chemical analyses were used to study the rock samples.
S. Wiesmaier, D. Morgavi, C. J. Renggli, D. Perugini, C. P. De Campos, K.-U. Hess, W. Ertel-Ingrisch, Y. Lavallée, and D. B. Dingwell
Solid Earth, 6, 1007–1023, https://doi.org/10.5194/se-6-1007-2015, https://doi.org/10.5194/se-6-1007-2015, 2015
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We reproduced in an experiment the mixing of two different magmas by bubbles. Bubbles form filaments when dragging portions of one magma into another and thus mingle both magmas. Bubble mixing must be an accelerating process in nature, because formed filaments are channels of low resistance for subsequently rising bubbles. In natural gas-rich magmas, this may be an important mechanism for magma mixing. Natural samples from Axial Seamount show evidence for bubble mixing.
M. Ledevin, N. Arndt, A. Davaille, R. Ledevin, and A. Simionovici
Solid Earth, 6, 253–269, https://doi.org/10.5194/se-6-253-2015, https://doi.org/10.5194/se-6-253-2015, 2015
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We investigate the composition, physical and rheological properties of fluids at the origin of Palaeoarchean chert dikes in South Africa. The dikes formed by repetitive hydraulic fracturing as overpressured oceanic fluids were released at low temperatures as a siliceous slurry. The gelation capacity of silica conferred the chert precursor a viscoelastic, probably thixotrope behaviour. It is an additional step to understand fluid circulations towards the ocean floor, the habitat of early life.
K. Jamshidi, H. Ghasemi, V. R. Troll, M. Sadeghian, and B. Dahren
Solid Earth, 6, 49–72, https://doi.org/10.5194/se-6-49-2015, https://doi.org/10.5194/se-6-49-2015, 2015
I. V. Ashchepkov, N. V. Alymova, A. M. Logvinova, N. V. Vladykin, S. S. Kuligin, S. I. Mityukhin, H. Downes, Yu. B. Stegnitsky, S. A. Prokopiev, R. F. Salikhov, V. S. Palessky, and O. S. Khmel'nikova
Solid Earth, 5, 915–938, https://doi.org/10.5194/se-5-915-2014, https://doi.org/10.5194/se-5-915-2014, 2014
S. Bouquain, N. T. Arndt, F. Faure, and G. Libourel
Solid Earth, 5, 641–650, https://doi.org/10.5194/se-5-641-2014, https://doi.org/10.5194/se-5-641-2014, 2014
V. R. Troll, A. Klügel, M.-A. Longpré, S. Burchardt, F. M. Deegan, J. C. Carracedo, S. Wiesmaier, U. Kueppers, B. Dahren, L. S. Blythe, T. H. Hansteen, C. Freda, D. A. Budd, E. M. Jolis, E. Jonsson, F. C. Meade, C. Harris, S. E. Berg, L. Mancini, M. Polacci, and K. Pedroza
Solid Earth, 3, 97–110, https://doi.org/10.5194/se-3-97-2012, https://doi.org/10.5194/se-3-97-2012, 2012
M. Nasrabady, F. Rossetti, T. Theye, and G. Vignaroli
Solid Earth, 2, 219–243, https://doi.org/10.5194/se-2-219-2011, https://doi.org/10.5194/se-2-219-2011, 2011
Cited articles
Adamson, A. W. and Gast, A. P.: Physical Chemistry of Surfaces,
Wiley, New York, 1997.
Alshibli, K. A. and Reed, A. H. (Eds.): Advances in Computed
Tomography for Geomaterials: GeoX 2010, Wiley, New York, 2012.
Archie, G. E.: The electrical
resisitivity log as an aid in determining some reservoir
characteristics, Soc. Petrol. Eng., 146, 54–62,
https://doi.org/10.2118/942054-G, 1942.
Arns, C., Knackstedt, F., M., and
Pinczewski, W.: Accurate estimation of transport properties from
microtomographic images, Geophys. Res. Lett., 28, 3361–3364,
2001.
Arns, C., Knackstedt, M., Pinczewski, W.,
and Garboczi, E.: Computation of linear elastic properties from
microtomographic images: methodology and agreement between theory
and experiment, Geophysics, 67, 1396–1405, 2002.
Arns, C., Bauget, F., Ghous, A.,
Sakellario, A., Senden, T., Sheppard, A., Sok, R., Pinczewski, W.,
Kelly, J., and Knackstedt, M.: Digital core laboratory:
petrophysical analysis from 3D imaging of reservoir core fragments,
Petrophysics, 46, 260–277, 2005a.
Arns, C., Bauget, F.,
Limaye, A., Sakellariou, A., Senden, T., Sheppard, A., Sok, R.,
Pinczewski, W., Bakke, S., Berge, L., Oren, R., and Knackstedt, M.:
Pore-scale characterization of carbonates using X-ray
microtomography, SPE J., 10, 475–484, 2005b.
Arns, C. H., Knackstedt, M. A.,
Pinczewski, W. V., and Martys, N. S.: Virtual permeametry on
microtomographic images, J. Petrol. Sci. Geol., 45, 41–46, 2004.
Baker, S. and Friedman, G. M.: A non-destructive core analysis
technique using X-rays, J. Sediment. Petrol., 39, 1371–1383,
1969.
Barrante, J. (Ed.): Applied
Mathematics for Physical Chemistry, Prentice-Hall, Englewood Cliffs,
New Jersey, 1974.
Becker, M. and Shapiro, A.: Interpreting tracer breakthrough tailing
from different forced-gradient tracer experiment configurations in
fractured bedrock, Water Resour. Res., 39, 1024, https://doi.org/10.1029/2001WR001190, 2003.
Bjerreskov, M.: Discoveries on graptolites by X-ray studies, Acta Palaeontol. Pol.,
21, 463–471, 1978.
Boving, T. B. and Grathwohl, P.: Tracer diffusion coefficients in
sedimentary rocks: correlation to porosity and hydraulic
conductivity, J. Contam. Hydrol., 53, 85–100,
https://doi.org/10.1016/S0169-7722(01)00138-3, 2001.
Bultreys, T., Boone, M., Boone, M., De Schryver, T., Masschaele, B.,
Van Hoorebeke, L., and Cnudde, V.: Fast laboratory-based
micro-computed tomography for pore-scale research: illustrative
experiments and perspectives on the future, Adv. Water Resour., 1–11,
https://doi.org/10.1016/j.advwatres.2015.05.012, 2015.
Calvert, S. E. and Veevers, J. J.: Minor structures of
unconsolidated marine sediments revealed by X-radiography,
Sedimentology, 1, 287–295,
https://doi.org/10.1111/j.1365-3091.1962.tb01151.x, 1962.
Carroll, S., Hao, Y., Smith, M., and
Sholokhova, Y.: Development of scaling parameters to describe
CO2–rock interactions within Weyburn-Midale carbonate flow
units, Int. J. Greenh. Gas Con., 16, S185–S193,
https://doi.org/10.1016/j.ijggc.2012.12.026,
2013.
Casteleyn, L., Robion, P.,
David, C., Collin, P.-Y., Menendez, B., Fernandes, N.,
Desaubliaux, G., and Rigollet, C.: An integrated study of the
petrophysical properties of carbonate rocks from the “Oolithe
Blanche” formation in the Paris Basin, Tectonophysics, 503, 18–33,
https://doi.org/10.1016/j.tecto.2010.09.031, 2011.
Cnudde, V. and
Boone, M.: High-resolution X-ray computed tomography in geosciences:
a review of the current technology and applications,
Earth-Sci. Rev., 123, 1–17,
https://doi.org/10.1016/j.earscirev.2013.04.003, 2013.
Coker, D. A. and Torquato, S.: Simulation of diffusion and trapping
in digitized heterogeneous media, J. Appl. Phys., 77, 955–964,
https://doi.org/10.1063/1.358940, 1995.
Crank, J.: The Mathematics of
Diffusion, Oxford University Press, Ely House, London, 1975.
Cui, X., Bustin, R., and Dipple, G.: Selective transport of
CO2, CH4, and N2 in coals: insights from
modeling of experimental gas adsorption data, Fuel, 83, 293–303,
https://doi.org/10.1016/j.fuel.2003.09.001, 2004.
Cui, X., Bustin, A. M. M., and Bustin, R. M.: Measurements of gas
permeability and diffusivity of tight reservoir rocks: different
approaches and their applications, Geofluids, 9, 208–223,
https://doi.org/10.1111/j.1468-8123.2009.00244.x, 2009.
Douissard, P.-A., Cecilia, A.,
Rochet, X., Chapel, X., Martin, T., Van De Kamp, T., Helfen, L.,
Baumbach, T., Luquot, L., Xiao, X., Meinhardt, J., and Rack, A.:
A versatile indirect detector design for hard X-ray microimaging,
J. Instrum., 7, P09016,
https://doi.org/10.1088/1748-0221/7/09/P09016,
2012.
Dunsmuir, J., Ferguson, S.,
D'Amico, K., and Stokes, J. P.: X-ray micro tomography. A new tool
for the characterization of porous media, SPE J., 22860,
https://doi.org/10.2118/22860-MS,
1991.
Einstein, A.: Investigations
on the Theory of the Brownian Movement, edited by: Furth, R.,
translated by: Cowper, A. D., Dover Publications, New York, 1956.
Elkhoury, J. E., Ameli, P., and
Detwiler, R. L.: Dissolution and deformation in fractured carbonates
caused by flow of CO2-rich brine under reservoir conditions,
Int. J. Greenh. Gas Con., 16S, S203–S215,
https://doi.org/10.1016/j.ijggc.2013.02.023,
2013.
Espinoza, D. N. and Santamarina, J. C.: Water CO2 mineral
systems: interfacial tension, contact angle, and diffusion
implication to CO2 geological storage, Water Resour. Res.,
46, W07537, https://doi.org/10.1029/2009WR008634, 2010.
Fick, A.: Ueber diffusion,
Ann. Phys., 170,
59–89, 1855.
Fredd, C. N. and Fogler, H. S.: Influence of transport and reaction
on wormhole formation in porous media, AIChE J., 44, 1933–1949,
1998.
Garing, C., Luquot, L., Pezard, P., and
Gouze, P.: Electrical and flow properties of highly heterogeneous
carbonate rocks, AAPG Bull., 98, 49–66,
https://doi.org/10.1306/05221312134,
2014.
Gillham, R. W., Sudicky, E. A.,
Cherry, J. A., and Frind, E. O.: An advection–diffusion concept for
solute transport in heterogeneous unconsolidated geological
deposits, Water Resour. Res., 20, 369–378,
https://doi.org/10.1029/WR020i003p00369, 1984.
Gouze, P. and
Luquot, L.: X-ray microtomography characterization of porosity,
permeability and reactive surface changes during dissolution,
J. Contam. Hydrol., 120–121, 44–55, 2011.
Hamblin, W.: X-ray radiography
in the study of structures in homogeneous sediments,
J. Sediment. Petrol., 32, 133–145, 1962.
Hatiboglu, C. U. and Babadagli, T.: Experimental and visual analysis
of diffusive mass transfer between matrix and fracture under static
conditions, J. Petrol. Sci. Eng., 74, 31–40,
https://doi.org/10.1016/j.petrol.2010.08.004, 2010.
Herm, D.: Paleontology,
Naturwissenschaften, 63, 81–86, 1973.
Hinai, A. A., Rezaee, R., Esteban, L.,
and Labani, M.: Comparisons of pore size distribution: a case from
the Western Australian gas shale formations, Journal of
Unconventional Oil and Gas Resources, 8, 1–13,
https://doi.org/10.1016/j.juogr.2014.06.002, 2014.
Hoshen, J. and Kopelman, R.: Percolation and cluster
distribution. I. Cluster multiple labeling technique and critical
concentration algorithm, Phys. Rev. B, 14, 3438–3445,
https://doi.org/10.1103/PhysRevB.14.3438, 1976.
Ketcham, R. A. and Carlson, W. D.: Acquisition, optimization and
interpretation of X-ray computed tomographic imagery: applications
to the geosciences, Comput. Geosci., 27, 381–400,
https://doi.org/10.1016/S0098-3004(00)00116-3, 2001.
Knackstedt, M. A., Arns, C. H.,
Saadatfar, M., Senden, T. J., Limaye, A., Sakellariou, A.,
Sheppard, A. P., Sok, R. M., Schrof, W., and Steininger, H.: Elastic
and transport properties of cellular solids derived from
three-dimensional tomographic images, P. Roy. Soc. Lond. A Mat.,
462, 2833–2862,
https://doi.org/10.1098/rspa.2006.1657, 2006.
Lamande, M., Wildenschild, D.,
Berisso, F. E., Garbout, A., Marsh, M., Moldrup, P., Keller, T.,
Hansen, S. B., de Jonge, L. W., and Schjonning, P.: X-ray CT and
laboratory measurements on glacial till subsoil cores: assessment of
inherent and compaction-affected soil structure characteristics,
Soil Sci., 178, 359–368,
https://doi.org/10.1097/SS.0b013e3182a79e1a, 2013.
Landry, C., Karpyn, Z., and Ayala, O.:
Pore-scale lattice Boltzmann modeling and 4D X-ray computed
microtomography imaging of fracture-matrix fluid transfer, Transport
Porous Med., 103, 449–468,
https://doi.org/10.1007/s11242-014-0311-x,
2014.
Lee, T.-C., Kashyap, R. L., and Chu, C.-N.: Building skeleton models
via 3-D medial surface axis thinning algorithms,
CVGIP-Graph. Model. Im., 56, 462–478,
https://doi.org/10.1006/cgip.1994.1042,
1994.
Li, Y.-H. and
Gregory, S.: Diffusion of ions in sea water and in deep-sea
sediments, Geochim. Cosmochim. Ac., 38, 703–714,
https://doi.org/10.1016/0016-7037(74)90145-8, 1974.
Louis, L., Wong, T.-F., and Baud, P.: Imaging strain localization by
X-ray radiography and digital image correlation: deformation bands
in Rothbach sandstone, J. Struct. Geol., 29, 129–140,
https://doi.org/10.1016/j.jsg.2006.07.015, 2007.
Luquot, L. and
Gouze, P.: Experimental determination of porosity and permeability
changes induced by injection of CO2 into carbonate rocks,
Chem. Geol., 265, 148–159, 2009.
Luquot, L., Rodriguez, O., and Gouze, P.:
Experimental characterization of porosity structure and transport
property changes in limestone undergoing different dissolution
regimes, Transport Porous Med., 101, 507–532,
https://doi.org/10.1007/s11242-013-0257-4, 2014a.
Luquot, L., Roetting, T., and
Carrera, J.: Characterization of flow parameters and evidence of
pore clogging during limestone dissolution experiments, Water
Resour. Res., 50, 6305, https://doi.org/10.1002/2013WR015193,
2014b.
Mangane, P. O., Gouze, P., and
Luquot, L.: Permeability impairment of a limestone reservoir
triggered by heterogeneous dissolution and particles migration
during CO2-rich injection, Geophys. Res. Lett., 40,
4614–4619,
https://doi.org/10.1002/grl.50595, 2013.
Martys, N., Hagedorn, J., Goujon, D.,
and Devaney, J.: Large scale simulations of single and
multi-component flow in porous media, SPIE, 3772, 309–403, 1999.
Mecke, K. R.: Additivity,
convexity, and beyond: application of Minkovski functionals in
statistical physics, Lect. Notes Phys., 554, 11–184,
2000.
Meijster, A., Roerdink, J. B., and
Hesselink, W. H.: A general algorithm for computing distance
transforms in linear time, in: Mathematical Morphology and its
Applications to Image and Signal Processing, Springer Science+Business Media, New York, 331–340,
2002.
Menke, H. P., Bijeljic, B., Andrew, M. G.,
and Blunt, M. J.: Dynamic three-dimensional pore-scale imaging of
reaction in a carbonate at reservoir conditions,
Environ. Sci. Technol., 49, 4407–4414,
https://doi.org/10.1021/es505789f,
2015.
Monna, F., Lancelot, J., Bernat, M.,
and Mercadier, H.: Sedimentation rate in the Thau Basin (France)
according to geochronological, geochemical and stratigraphical data,
Oceanol. Acta, 20, 627–638, 1997.
Nestle, N., Galvosas, P., Geier, O., Dakkouri, M., Zimmermann, C.,
and Kärger, J.: {NMR} studies of water diffusion and
relaxation in hydrating slag-based construction materials,
Magn. Reson. Imaging, 19, 547–548,
https://doi.org/10.1016/S0730-725X(01)00301-0, 2001a.
Nestle, N.,
Zimmermann, C., Dakkouri, M., and Niessner, R.: Action and
distribution of organic solvent contaminations in hydrating cement:
time-resolved insights into solidification of organic waste,
Environ. Sci. Technol., 35, 4953–4956,
https://doi.org/10.1021/es015528y,
2001b.
Nimmo, J.: Porosity and pore size
distribution, in: Encyclopedia of Soils in the Environment, edited
by: Hillel, D., Elsevier, London, 295–303, 2004.
Noiriel, C., Luquot, L.,
Made, B., Raimbault, L., Gouze, P., and van der Lee, J.: Changes in
reactive surface area during limestone dissolution: an experimental
and modelling study, Chem. Geol., 265, 160–170, 2009.
Peng, S., Hu, Q., and Hamamoto, S.: Diffusivity of rocks: gas
diffusion measurements and correlation to porosity and pore size
distribution, Water Resour. Res., 48, w02507,
https://doi.org/10.1029/2011WR011098, 2012.
Prodanovic, M., Bryant, S. L., and
Karpyn, Z. T.: Investigating matrix/fracture transfer via a level
set method for drainage and imbibition, SPE J., 15, 125–136,
https://doi.org/10.2118/116110-PA, 2010.
Promentilla, M., Sugiyama, T.,
Hitomi, T., and Takeda, N.: Quantification of tortuosity in hardened
cement pastes using synchrotron-based X-ray computed
microtomography, Cement Concrete Res., 39, 548–557,
https://doi.org/10.1016/j.cemconres.2009.03.005, 2009.
Reatto, A., da Silva, E., Bruand, A.,
Martins, E., and Lima, J.: Validata of the centrifuge method for
determining the water retention properties of tropical soils, Soil
Sci. Soc. Am. J., 72, 1547–1553, 2008.
Remeysen, K. and Swennen, R.: Application of microfocus computed
tomography in carbonate reservoir characterization: possibilities
and limitations, Mar. Petrol. Geol., 25, 486–499,
https://doi.org/10.1016/j.marpetgeo.2007.07.008, 2008.
Roberts, A. P. and Garboczi, E. J.: Elastic properties of model
porous ceramics, J. Am. Ceram. Soc., 83, 3041–3048,
https://doi.org/10.1103/PhysRevE.54.2313, 2000.
Robinson, R. and Stokes, R. H.: Electrolyte Solutions: the
Measurement and Interpretation of Conductance, Chemical Potential and
Diffusion in Solutions of Simple Electrolytes, Academic press University of New England, New York, Butterworths,
1959.
Roetting, T. S., Luquot, L.,
Carrera, J., and Casalinuovo, D. J.: Changes in porosity,
permeability, water retention curve and reactive surface area during
carbonate rock dissolution, Chem. Geol., 403, 86–98,
https://doi.org/10.1016/j.chemgeo.2015.03.008, 2015.
Schmidt, S., Jouanneau, J.-M., Weber, O., Lecroart, P.,
Radakovitch, O., Gilbert, F., and Jézéquel, D.: Sedimentary
processes in the Thau Lagoon (France): from seasonal to century time
scales, Estuar. Coast. Shelf S., 72, 534–542,
https://doi.org/10.1016/j.ecss.2006.11.019, 2007.
Schwartz, L. M.,
Auzerais, F., Dunsmuir, J., Martys, N., Bentz, D. P., and
Torquato, S.: Transport and diffusion in three-dimensional composite
media, Physica A, 207, 28–36, 1994.
Sen, P. N.: Time-dependent diffusion
coefficient as a probe of geometry, Concept. Magn. Reson. A, 23,
1–21,
https://doi.org/10.1002/cmr.a.20017, 2004.
Siddiqi, K. and Pizer, S.: Medial Representations: Mathematics,
Algorithms and Applications, 1st Edn., Springer Publishing Company,
Incorporated, the Netherlands, 2008.
Smith, M. M., Sholokhova, Y., Hao, Y.,
and Carroll, S. A.: CO2-induced dissolution of low
permeability carbonates. Part I: Characterization and experiments,
Adv. Water Resour., 62, 370–387,
https://doi.org/10.1016/j.advwatres.2013.09.008, 2013.
Sturmer, W.: X-ray photography
in paleontology-some new results, Naturwissenschaften, 60, 407–411,
1973.
Taina, I. A., Heck, R. J., and Elliot, T. R.: Application of X-ray
computed tomography to soil science: a literature review, Can.
J. Soil Sci., 88, 1–19,
https://doi.org/10.4141/CJSS06027, 2008.
Torquato, S.: Random
Heterogeneous Materials: Microstructure and Macroscopic Properties,
Springer-Verlag, New York, 2002.
van Brakel, J. and Heertjes, P.: Analysis of diffusion in
macroporous media in terms of a porosity, a tortuosity and
a constrictivity factor, Int. J. Heat Mass Tran., 17, 1093–1103,
https://doi.org/10.1016/0017-9310(74)90190-2, 1974.
Vogel, H.-J., Weller, U., and
Schlüter, S.: Quantification of soil structure based on
Minkowski functions, Comput. Geosci., 36, 1236–1245,
https://doi.org/10.1016/j.cageo.2010.03.007, 2010.
Wildenschild, D. and Sheppard, A. P.: X-ray imaging and analysis techniques
for quantifying pore-scale structure and processes in subsurface porous
medium systems, Adv. Water Resour., 51, 217–246,
https://doi.org/10.1016/j.advwatres.2012.07.018, 2013.
Short summary
To evaluate oil and gas production, accurate characterization (usually based on laboratory experiments) of reservoir rock properties needs to be performed. X-ray scanning samples enable obtaining 3-D images of the rock inner structure from which those properties can be obtained using images processing. This article shows that these two approaches are complementary and yield consistent results. Moreover, image-based calculations allow to save a huge amount of time compared to lab-based measures.
To evaluate oil and gas production, accurate characterization (usually based on laboratory...
