Articles | Volume 9, issue 1
https://doi.org/10.5194/se-9-223-2018
https://doi.org/10.5194/se-9-223-2018
Research article
 | 
27 Feb 2018
Research article |  | 27 Feb 2018

Structural disorder of graphite and implications for graphite thermometry

Martina Kirilova, Virginia Toy, Jeremy S. Rooney, Carolina Giorgetti, Keith C. Gordon, Cristiano Collettini, and Toru Takeshita

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Cited articles

Barzoi, S. C.: Shear stress in the graphitization of carbonaceous matter during the low-grade metamorphism from the northern Parang Mountains (South Carpathians) – Implications to graphite geothermometry, Int. J. Coal Geol., 146, 179–187, 2015.
Beeler, N. M.: Laboratory-observed faulting in intrinsically and apparently weak materials: Strength, seismic coupling, dilatancy, and pore-fluid pressure, The Seismogenic Zone of Subduction Thrust Faults, 370–449, 2007.
Beyssac, O., Goffé, B., Chopin, C., and Rouzaud, J. N.: Raman spectra of carbonaceous material in metasediments: a new geothermometer, J. Metamorph. Geol., 20, 859–871, 2002a.
Beyssac, O., Rouzaud, J. N., Goffé, B., Brunet, F., and Chopin, C.: Graphitization in a high-pressure, low-temperature metamorphic gradient: a Raman microspectroscopy and HRTEM study, Contrib. Mineral. Petr., 143, 19–31, 2002b.
Beyssac, O., Brunet, F., Petitet, J. P., Goffé, B., and Rouzand, J. N.: Experimental study of the microtextural and structural transformations of carbonaceous materials under pressure and temperature, Eur. J. Mineral., 15, 937–951, 2003.
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Short summary
Graphite crystallinity “irreversibly” increases with temperature and it has been calibrated as a thermometer recording peak temperatures experienced by a rock. To examine the possibility of mechanical modifications of graphite structure and the impacts on graphite thermometry we performed deformation experiments. Raman spectroscopy demonstrates a reduction in crystallinity due to mechanical reworking in the brittle field. This finding clearly compromises the validity of the graphite thermometry.